FAQ: What is the relative activity of APOBEC3A (NEB #M0648) on different modified dC-containing ssDNA substrates?

While APOBEC3A has a preferred substrate of C-containing ssDNA, it will deaminate 5mC-containing ssDNA with 2-fold less activity in a 30-minute reaction under recommended reaction conditions. In an overnight incubation (16 hours), APOBEC3A can reach complete deamination of 5mC-containing ssDNA and can deaminate 5-hydroxymethylcytosine (5hmC)-containing ssDNA less than 10%. APOBEC3A is not active on ssDNA containing beta-glucosyl-5-hydroxymethylcytosine (5gmC), 5-carboxylcytosine (5caC), or 5-formylcytosine (5fC).


ssDNA Modification Activity after 30 min. Activity after 16 h
C to U 100% 100%
5mC to T 50% 100%
5hmC to 5hmU 0% <10%
5fC to 5fU 0% 0%
5caC to 5caU 0% 0%
5gmC to 5gmU 0% 0%

 

Line graph depicting substrate specificity of APOBEC3A

Activity on modified C ssDNA substrates was determined by incubating 1 µl of APOBEC3A with 1 μg (73 pmol) of a 44-mer DNA oligo containing a single C or modified C at 37°C in a total reaction volume of 40 µl in 1X Deamination Reaction Buffer. Samples were heat inactivated at each time point then analyzed by LCMS.

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APOBEC3A